During the course of my research, I had had occasion to examine not only simple compounds, salts and oxides, but also a great number of minerals. Certain ones proved radioactive; these were those containing uranium and thorium; but their radioactivity seemed abnormal, for it was much greater than the amount I had found in uranium and thorium had led me to expect.
This abnormality greatly surprised us. When I had assured myself that it was not due to an error in the experiment, it became necessary to find an explanation. I then made the hypothesis that the ores uranium and thorium contain in small quantity a substance much more strongly radioactive than either uranium or thorium. This substance could not be one of the known elements, because these had already been examined; it must, therefore, be a new chemical element.
I had a passionate desire to verify this hypothesis as rapidly as possible. And Pierre Curie, keenly interested in the question, abandoned his work on crystals (provisionally, he thought) to join me in the search for this unknown substance.
We chose, for our work, the ore pitchblende, a uranium ore, which in its pure state is about four times more active than oxide of uranium. Since the composition of this ore was known through very careful chemical analysis, we could expect to find, at a maximum, per cent of new substance. The result of our experiment proved that there were in reality new radioactive elements in pitchblende, but that their proportion did not reach even a millionth per cent!
The method we employed is a new method in chemical research based on radioactivity. It consists in inducing separation by the ordinary means of chemical analysis, and of measuring, under suitable conditions, the radioactivity of all the separate products. By this means one can note the chemical character of the radioactive element sought for, for it will become concentrated in those products which will become more and more radioactive as the separation progresses. We soon recognized that the radioactivity was concentrated principally in two different chemical fractions, and we became able to recognize in pitchblende the presence of at least two new radioactive elements: polonium and radium. We announced the existence of polonium in July, , and of radium in December of the same year.
In spite of this relatively rapid progress, our work was far from finished. In our opinion, there could be no doubt of the existence of these new elements, but to make chemists admit their existence, it was necessary to isolate them. Now, in our most strongly radioactive products (several hundred times more active than uranium), the polonium and radium were present only as traces. The polonium occurred associated with bismuth extracted from pitchblende, and radium accompanied the barium extracted from the same mineral. We already knew by what methods we might hope to separate polonium from bismuth and radium from barium; but to accomplish such a separation we had to have at our disposition much larger quantities of the primary ore than we had. It was during this period of our research that we were extremely handicapped by inadequate conditions, by the lack of a proper place to work in, by the lack of money and of personnel.
Pitchblende was an expensive mineral, and we could not afford to buy a sufficient quantity. At that time the principal source of this mineral was at St. Joachimsthal (Bohemia) where there was a mine which the Austrian government worked for the extraction of uranium. We believed that we would find all the radium and a part of the polonium in the residues of this mine, residues which had so far not been used at all. Thanks to the influence of the Academy of Sciences of Vienna, we secured several tons of these residues at an advantageous price, and we used it as our primary material. In the beginning we had to draw on our private resources to pay the costs of our experiment; later we were given a few subventions and some help from outside sources.
The question of quarters was particularly serious; we did not know where we could conduct our chemical treatments. We had been obliged to start them in an abandoned storeroom across a court from the workroom where we had our electrometric installation. This was a wooden shed with a bituminous floor and a glass roof which did not keep the rain out, and without any interior arrangements. The only objects it contained were some worn pine tables, a cast-iron stove, which worked badly, and the blackboard which Pierre Curie loved to use. There were no hoods to carry away the poisonous gases thrown off in our chemical treatments, so that it was necessary to carry them on outside in the court, but when the weather was unfavorable we went on with them inside, leaving the windows open. A view of the extraction of radium in the old shed where the first radium was obtained
